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Preparation of transparent, electrically conducting ZnO film from zinc acetate and alkoxide

Identifieur interne : 000164 ( Main/Exploration ); précédent : 000163; suivant : 000165

Preparation of transparent, electrically conducting ZnO film from zinc acetate and alkoxide

Auteurs : RBID : ISTEX:10853_1994_Article_BF00355977.pdf

Abstract

Very uniform and transparent zinc oxide thin films doped with aluminium and indium were fabricated by the dip-coating technique using solutions prepared by the ethanolamine method. As starting materials, zinc acetate and zinc n-propoxide were used. Zinc acetate and propoxide are soluble in PriOH in the presence of diethanolamine, although they are hardly soluble without the amine. The prepared solutions were very stable and suitable for dip-coating. Zinc oxide was crystallized by heating above 500 °C, and doping of aluminium and indium retarded the crystallization. The electrical resistivity of the film was decreased by doping with aluminium and indium. The lowest resistivity of 2 × 10−2 Ωcm was obtained by post-coating treatment in a nitrogen atmosphere.

DOI: 10.1007/BF00355977

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<div type="abstract" xml:lang="eng">Very uniform and transparent zinc oxide thin films doped with aluminium and indium were fabricated by the dip-coating technique using solutions prepared by the ethanolamine method. As starting materials, zinc acetate and zinc n-propoxide were used. Zinc acetate and propoxide are soluble in PriOH in the presence of diethanolamine, although they are hardly soluble without the amine. The prepared solutions were very stable and suitable for dip-coating. Zinc oxide was crystallized by heating above 500 °C, and doping of aluminium and indium retarded the crystallization. The electrical resistivity of the film was decreased by doping with aluminium and indium. The lowest resistivity of 2 × 10−2 Ωcm was obtained by post-coating treatment in a nitrogen atmosphere.</div>
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<abstract lang="eng">Very uniform and transparent zinc oxide thin films doped with aluminium and indium were fabricated by the dip-coating technique using solutions prepared by the ethanolamine method. As starting materials, zinc acetate and zinc n-propoxide were used. Zinc acetate and propoxide are soluble in PriOH in the presence of diethanolamine, although they are hardly soluble without the amine. The prepared solutions were very stable and suitable for dip-coating. Zinc oxide was crystallized by heating above 500 °C, and doping of aluminium and indium retarded the crystallization. The electrical resistivity of the film was decreased by doping with aluminium and indium. The lowest resistivity of 2 × 10−2 Ωcm was obtained by post-coating treatment in a nitrogen atmosphere.</abstract>
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